Graphene Dots Embedded Phosphide Nanosheet-Assembled Tubular Arrays for Efficient and Stable Overall Water Splitting

Bifunctional electrocatalysts are highly desired for overall water splitting. Herein, the design and fabrication of three-dimensional (3D) hierarchical earth-abundant transition bimetallic phosphide arrays constructed by one-dimensional tubular array that was derived from assembling two-dimensional nanosheet framework has been reported by tailoring the Co/Ni ratio and tunable morphologies, and zero-dimensional (0D) graphene dots were embedded on Co–Ni phosphide matrix to construct 0D/2D tubular array as a highly efficient electrode in the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). On the basis of advanced merits, such as the high surface-active sites, well-dispersed graphene dots, and enhanced electron transfer capacity as well as the confinement effect of the graphene dots on the nanosheets, the integrated GDs/Co 0.8 Ni 0.2 P tubular arrays as anode and cathode exhibit excellent OER and HER performance. By use of GDs/Co 0.8 Ni 0.2 P arrays in the two-electrode setup of the device, a remarkable electrocatalytic performance for full water splitting has been achieved with a high current density of 10 mA cm –2 at 1.54 V and outstanding long-term operation stability in an alkaline environment, indicating a promising system based on nonprecious-metal electrocatalysts toward potential practical devices of overall water splitting.