Metallo-supramolecular AB block copolymers are the first examples of macromolecular engineeering. A new concept for the formation of block copolymers by a supramolecular approach is presented. For this purpose the authors utilized an asymmetrical bis(terpyridine)–ruthenium complex as the supramolecular linkage between the two blocks (see figure).
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Lohmeijer et al. (2002) studied this question.
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