RhIII‐catalyzed hydroarylation of internal alkynes through C−H bond activation is described herein by using N,N‐dimethylaminocarbonyl as a directing group without the need of an external oxidant. This protocol exhibits exceptional functionality compatibility owing to its extremely mild reaction conditions, which provides a facile and highly efficient synthetic method for olefin moiety introduction.
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Wang et al. (2016) studied this question.
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