The presence of a certain degree of crystallinity in poly(1.2‐dichloroalkamer)s, obtained by addition chlorination of a homologous series of stereoregular polyalkenamers, ranging from polybutenamer to polydodecenamer, may suggest a chain mechanism for chlorine addition. Three different approaches have been used in order to support such a mechanism by experimental evidences: Determination of the relative velocities of chlorine addition to the two double bonds of different dienes, used as model compounds of polyalkenamers. Investigation of the demolition products of partially chlorinated polyalkenamers. Examination of the DTA thermograms of partially chlorinated polyalkenamers.
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Dall'Asta et al. (1972) studied this question.
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