Nylon 6,6 single‐crystal scrolls and tubes (see Figure) have been created through self‐seeding solution crystallization. The tube diameter is ∼ 350 nm with a ∼ 10 nm thin wall. The tubular/scroll single crystal form is presumably due to the asymmetric folding of Nylon 6,6, which can be turned on and off by controlling the self‐seeding temperature.
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Cai et al. (2004) studied this question.
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