Two local vibrational modes related to hydrogen in GaN

We have observed two absorption bands located at around 1730 and 2960 cm−1 in the infrared (IR) absorption spectra from undoped GaN samples which are grown using low pressure metalorganic vapor phase epitaxy and irradiated by gamma ray and then exposed to a radio frequency hydrogen plasma. Proton implantation followed by gamma-ray irradiation of the GaN samples can also activate the IR band at around 1730 cm−1. Based on the experimental results, we tentatively ascribe the 1730 cm−1 band to the local vibrational modes of Ga–H complexes in the vicinity of N vacancies and the 2960 cm−1 band to those of either N–H complexes in the vicinity of Ga vacancies or C–H complexes.