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In order to study the interaction of cysteine containing peptide chains with Hg(II) the nuclear quadrupole interaction (NQI) of 199mHg in the Hg complex of the oligopeptide Alanine-Alanine-Cysteine-Alanine-Alanine (AACAA) was determined by time differential perturbed angular correla-tion. Different 199mHg-NQI’s for free and resin-bound AACAA were obtained. Furthermore, the 199mHg-NQI’s are influenced by the Hg:AACAA stoichiometry.
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Tröger et al. (1996) studied this question.
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