A series of A-frame Pt(II) acetylide complexes [Pt 2 (μ-dppm) 2 (μ-C⋮CR)(C⋮CR) 2 ] + (R = C 6 H 5, C 6 H 4 OMe- p, C 6 H 4 OEt- p, C 6 H 4 Et- p, Bp, t Bu) have been isolated and shown to exhibit strong luminescence in both the solid state and in fluid solution. All these A-frame acetylide complexes have been found to exhibit fluxional properties. The free energies of activation for the fluxional process of selected Pt(II) A-frame acetylide complexes have been determined.
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Yam et al. (1998) studied this question.
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