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September 1, 2006Advanced Synthesis & Catalysis

Efficient Enantioselective Hydrosilylation of Aryl Ketones Catalyzed by a Chiral BINAP‐Copper( I ) Catalyst‐Phenyl(methyl)silane System

Jean Thomas Issenhuth Samuel Dagorne Stéphane Bellemin‐Laponnaz

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Abstract

The Cu(I)‐chiral diphosphine (BINAP) system was found to efficiently catalyze the hydrosilylation of aryl alkyl ketones with excellent enantioselectivities by using phenyl(methyl)silane as stoichiometric hydride source.

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Issenhuth et al. (2006) studied this question.

synapsesocial.com/papers/6a93fc9cc37eedbd3300dc4a https://doi.org/10.1002/adsc.200606152

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