Abstract (1) A study of the four sulfur atoms in tetramethylthiuram disulfide (TMTD) by radiosulfur techniques disclosed that these sulfur atoms are equivalent chemically. (2). The synthesis and reactions of radio‐TMTD were studied. (3) New reactions which were found for TMTD included those with the following substances: dimethylamine, n‐dodecyl mercaptan, ZnS, ZnO, zinc dust, S8*, and acetic acid. (4) Radiosulfur and the sulfur atoms in ZnDMDC do not undergo interchange, at least up to 150°.
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Craig et al. (1951) studied this question.
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