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New dendrimers 3-[G‘ 1 ]−3-[G‘ 4 ] possessing from 6 to 48 N(CH 2 PPh 2 ) 2 terminal groups are described. The corresponding Pd, Pt, and Rh complexes [N(CH 2 PPh 2 ) 2 MRR‘] y ( y from 6 to 24; generations 1−3) [M = Pd: R = R‘ = Cl, Br; R = Cl, R‘ = Me; R = Br, R‘ = Me; R = Cl, R‘ = COMe; R = Cl, R‘ = norbornyl-COMe. M = Pt: R = R‘ = Br, Cl, Me; R = Br, R‘ = Me. M = Rh: R, R‘ = acac] are prepared by reacting 3-[G‘ 1 ]−3-[G‘ 3 ] with the appropriate transition metal complexes.
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Bardají et al. (1997) studied this question.
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