The synthesis and characterization of a butadiyne linked Rh(III) porphyrin dimer containing a 4,4‘-bipyridine ligand are presented. The crystal structure is compared to the crystal structures of complexes of a monomeric Rh porphyrin with 4,4‘-bipyridine and pyridine, and with the results of molecular modeling.
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Kim et al. (1999) studied this question.
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