A ring-opening polymerization of glycidyl phenyl ether (GPE) was performed with a metal-free tetra-n-butylammonium acetate (Bu4NOAc). The polymerization of GPE initiated by Bu4NOAc enables to control the molecular weight of poly(GPE). This metal-free GPE polymerization system with Bu4NOAc is useful, because the hydroxyl terminated telechelic polymer with narrow molecular weight distribution is facilely obtained.
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Morinaga et al. (2011) studied this question.
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