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Silver(I) catalyzed oxidation of aspartic acid by cerium(IV) was studied in acid perchlorate medium. The stoichiometry of the reaction is represented by the eq. (i) equation image Dimeric cerium(IV) species has been indicated and employed in calculations of monomeric cerium(IV) species concentrations. The reaction is second‐order and uncatalyzed reaction also simultaneously occurs along with the silver(I) catalyzed reaction conforming to the rate law (ii) equation image wherekis an observed second‐order rate constant. A probable reaction mechanism is suggested.
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Sharma et al. (1995) studied this question.
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