By resorting to some results in quantum field theories with spontaneous breakdown of symmetry, we show that an explanation based on microscopic dynamics can be given for the fact that topological defect formation is observed during the process of non-equilibrium phase transitions characterized by a non-zero order parameter. We show that the Nambu–Goldstone particle acquires an effective non-zero mass due to boundary (finite volume) effects and this is related to the size of the defect. We also relate such volume effects with temperature effects.
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Alfinito et al. (2002) studied this question.
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