The e.m.f. of the cell Ag, AgCl/NaCl solution/sodium sensitive glass electrode was measured at 25°C. In pure water as a solvent, measured activity coefficients agree with tabulated osmotically determined values; hence, the ideality of the sodium response of the glass electrode is confirmed. Choosing a Tris – Tris. HCl buffer of the constant ionic strength 0,5M as a solvent, the applicability of HARNED'S rule was demonstrated. Conditions for measuring sodium ion concentrations with sodium sensitive glass electrodes are discussed.
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Schindler et al. (1968) studied this question.
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