High-Performance Co3O4 Nanoparticle-Based Gas Sensor for Leakage Detection of Eco-Friendly Insulating Gas C4F7N

Perfluoroisobutyronitrile (C 4 F 7 N), an eco-friendly insulating gas, has been extensively utilized in diverse gas-insulated equipment (GIE) to replace the most potent greenhouse gas SF 6 . Nonetheless, given the low toxicity of C 4 F 7 N, the potential leakage risk at a high-pressure operational environment cannot be overlooked, making the development of highly sensitive gas sensors for leak detection essential. Herein, Co 3 O 4 was selected as a specific gas sensing material for C 4 F 7 N detection based on the density functional theory screening. The Co 3 O 4 -based gas sensor was prepared, and its response performance was systematically evaluated. The interaction mechanism between Co 3 O 4 and C 4 F 7 N was also examined by the oxygen vacancy theory. The sensor demonstrates a low detection limit of 0.15 ppm at its optimal operating temperature of 300 °C, exhibiting exceptional selectivity and repeatability, with a stability response time of 55.5 s and recovery time of 1478 s. The sensor’s application potential under actual working settings was validated using a simulated leakage test. Relevant results provide guidance for the leakage monitoring of the C 4 F 7 N-based GIE.