A novel thermally biased mechanical energy conversion cycle

This paper demonstrates a new power cycle for direct conversion of mechanical energy into electrical energy under a thermal bias. The cycle consisted sequentially of (i) an electric poling process under zero stress, (ii) an isoelectric process consisting of applying a uniaxial compressive stress σH followed by (iii) an electric de-poling process under constant compressive stress, and finally (iv) an isoelectric process consisting of removing the compressive stress. The new cycle was performed at constant bias-temperature Tb. It was demonstrated on [001]-poled 0.72PbMg1∕3Nb2∕3O3-0.28PbTiO3 single crystals. The power density increased with increasing cycle frequency and compressive stress for frequency up to 1 Hz. Maximum energy and power densities of 44 J/l/cycle and 44 W/l were achieved at 1 Hz for bias-temperature Tb of 80 °C and electric field cycled between 0.2 and 0.8 MV/m with compressive stress σH = 25.13 MPa. This was attributed to a tetragonal-monoclinic-orthorhombic phase transition sequence. The material efficiency reached up to 87% and exceeded that of a similar thermomechanical power cycle performed on pyroelectric material. Finally, a physical model predicting the power density was derived and yielded accurate predictions of experimental data for all bias-temperatures considered and cycle frequency up to 1 Hz.