The photoemission spectra of NiS in both antiferromagnetic and Pauli paramagnetic phases show similar characteristic features of localized d electrons. This finding is in contrast with the results of band-structure calculations which predict drastic spectral changes between the two phases. It is suggested that fluctuations of the Ni 3d local moments due to hybridization with S 3p states near the Fermi level are responsible for the Pauli paramagnetic behavior.
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Fujimori et al. (1988) studied this question.
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