Rotational analyses have been carried out on the (1-0), (() 0), and (() 1) bands of the system of the TiO molecule, at 6651,7054, and 7590 A, respectively. In addition to providing the molecular constants presented in Table 4, the analysis showed that the system was produced by a 3A - ll transition, and not by a - H transition, as has been formerly assumed.
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John G. Phillips (1951) studied this question.