A cage comprising four gallium and four chlorine atoms (shown on the right) is the characteristic feature of the first dimeric digallane 1 (R = Si(SiMe3)3) having two different substituents. It is synthesized together with the tetrasilyl-substituted digallane 2 from Ga[GaCl4] and LiSi(SiMe3)3(THF)3.
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Linti et al. (1996) studied this question.
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