The isolated (1:1) complex of para-chlorofluorobenzene with water has been investigated by IR/R2PI depletion spectroscopy and ab initio calculations on the geometry and IR spectra. Whereas three different isomers (σF, σCl, π) were located by theory, in the molecular beam experiments only the two σ isomers have been observed.
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Riehn et al. (2001) studied this question.
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