Experimental data on chemical composition, atomic structure and electronic structure strongly suggests that titanium oxycarbide, TiOxC1-x, a mixed phase of TiO and TiC, is formed on the surface when a TiC (100) surface is exposed to oxygen and is then heated at ∼1000°C in an ultra-high vacuum.
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Oshima et al. (1983) studied this question.
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