A thermally stable, fluorous oxime-based palladacycle has been developed and was shown to efficiently promote various carbon–carbon bond formation reactions (Suzuki–Miyaura, Sonogashira and Stille) in aqueous media under microwave irradiation. The palladacycle gave extremely low levels of Pd leaching and could be reused five times with no significant loss of activity.
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Susanto et al. (2011) studied this question.
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