Asymmetries in the line intensities of component lines of electric-quadrupole doublets in M\"ossbauer spectra (the Karyagin effect) have been observed in linear chain-polycrystalline polymers over a wide range of temperatures. It was observed that the asymmetry increases at higher temperatures and almost disappears at low temperatures. No significant Karyagin effect has been observed for three-dimensional monomeric material.
No takes yet. Share an insight, caveat, or question.
Stöckler et al. (1968) studied this question.
Synapse has enriched 3 closely related papers on similar clinical questions. Consider them for comparative context: