High-Energy-Level Blue Phosphor for Solution-Processed White Organic Light-Emitting Diodes with Efficiency Comparable to Fluorescent Tubes

A high-energy-level blue phosphor FIr- p -OC 8 has been developed for solution-processed white organic light-emitting diodes (WOLEDs) with comparable fluorescent tube efficiency. Benefiting from the electron-donating nature of the introduced alkoxy, FIr- p -OC 8 shows not only efficient blue light but also elevated highest occupied molecular orbital/lowest unoccupied molecular orbital levels to well match the dendritic host H2. Consequently, the hole scattering between FIr- p -OC 8 and H2 can be prevented to favor the direct exciton formation on the blue phosphor, leading to reduced driving voltage and thus improved power efficiency. By exploiting this approach, a maximum power efficiency of 68.5 lm W −1 is achieved for FIr- p -OC 8 -based white devices, slightly declining to 47.0 lm W −1 at a practical luminance of 1,000 cd m −2 . This efficiency can be further raised to 96.3 lm W −1 @ 1,000 cd m −2 when a half-sphere is applied to increase light out-coupling. We believe that our results can compete with commercial fluorescent tubes, representing an important progress in solution-processed WOLEDs.