Furocoumarin hydroperoxides such as 1 are novel photochemical sources of hydroxyl radicals; in salmon testes DNA they form the mutagenic oxidation product 8-hydroxy-2'-deoxyguanosine 2 in up to 1.8% yield on UVA irradiation (λ = 350 nm).
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Adam et al. (1995) studied this question.
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