γ-C−H agostic stabilization of the 14-electron metal center by a saturated hydrocarbon group characterizes the structure of the first neutral, three-coordinate alkylrhodium(I) complex [(κ2-dtbpm)RhNp] (1; dtbpm = bis(di-tert-butylphosphanyl)methane, Np=neopentyl). Some of its reactions, for example, N2 complexation and C−H bond activation, are reported.
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Urtel et al. (2001) studied this question.
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