A naturally occurring optically active cyclitol, l-quebrachitol (1l-2-O-methyl-chiro-inositol), was stereoselectively transformed into myo-inositol derivatives via an oxidation-reduction process. The methyl ether was cleaved chemoselectively with AlCl3–NaI in the presence of a cis-cyclohexylidene moiety with d-myo-inositol 1-phosphate being efficiently obtained.
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Akiyama et al. (1992) studied this question.
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