A new thermal coupling reaction forms silyloxy imidoyl tellurides 2 from silyl tellurides 1, carbonyl compounds, and phenyl isocyanide [Eq. (1)]. A mechanism that involves the generation of the silyl radical from the silyl telluride and subsequent chemoselective coupling with carbonyl compounds and the isocyanide is proposed.
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Miyazoe et al. (2000) studied this question.
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