Access to sulfondiimines: The oxidative one-pot chlorination–imination sequence of in situ generated free sulfilimines by N-chlorosuccinimide (NCS) allows the preparation of N-monosubstituted sulfondiimines under mild reaction conditions with excellent functional-group tolerance (see scheme; Mes=2,4,6-trimethylphenylsulfonyl)
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Candy et al. (2012) studied this question.
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