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March 20, 2012Angewandte Chemie

Synthesis of Sulfondiimines by N‐Chlorosuccinimide‐Mediated Oxidative Imination of Sulfiliminium Salts

Mathieu Candy Carole Guyon Stefanie Mersmann Jia‐Rong Chen Carsten Bolm

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Abstract

Zugang zu Sulfondiiminen: Die oxidative Eintopf-Chlorierungs-Iminierungs-Sequenz von in situ generierten freien Sulfiliminen durch N-Chlorsuccinimid (NCS) ermöglicht die Synthese von N-monosubstituierten Sulfondiiminen unter milden Reaktionsbedingungen und mit hoher Toleranz gegenüber funktionellen Gruppen (siehe Schema, Mes=2,4,6-Trimethylphenylsulfonyl).

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Candy et al. (2012) studied this question.

synapsesocial.com/papers/6a94c998d77447fad79f6bf3 https://doi.org/10.1002/ange.201201296

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