Study of the Layered Magnetoresistive Perovskite La1.2Sr1.8Mn2O7 by High-Resolution Electron Microscopy and Synchrotron X-ray Powder Diffraction

The layered manganite La 1.2 Sr 1.8 Mn 2 O 7 is important in that it displays giant negative magnetoresistance properties, and its study complements the growing body of what we know about the complex size−charge−temperature−magnetic field parameter space of the perovskites A III 1 - x A‘ II x MnO 3 . We report here the results of a detailed characterization of the microstructure and structure of this layered phase by high-resolution electron microscopy and synchrotron X-ray powder diffraction (SXPD). The high resolution of the data has permitted the quantification of stacking faults. The SXPD data have also been treated using Rietveld analysis. We reexamine the magnetic and transport properties of this phase. The study highlights the importance of the two-dimensional (2D) nature of the title phase.