The synthesis of [RhF(COD)]n and its triphenylphosphine adduct 2, and a preliminary study of the reactivity of 2 are reported. The reactivity of the Rh−F bond is illustrated by the reactions that lead to compounds 5 and 6. Compound 5 is the first trifluoromethyl Rh(I) complex characterized by monocrystal X-ray diffraction. Both compounds 2 and 6 are initiators of the polymerization of phenylacetylene.
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Vicente et al. (2001) studied this question.
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