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A family of 16 new lipophilic 12-, 15-, and 18-membered ring, ester and amide-sidearmed lariat ethers has been prepared, characterized, and studied. It is found that alkali metal cation transport in a bulk CHCl3 membrane correlates well with both log Ks determined in CH3OH and with picrate extraction constants determined in the membrane solvent mixture.
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Hernandez et al. (1991) studied this question.
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