A highly enantioselective carbonyl‐ene reaction of trifluoropyruvate catalyzed by a recyclable indium(III)‐pybox complex in ionic liquid afforded trifluoromethyl‐containing tertiary homoallylic alcohols with excellent yields (up to 98%) and enantioselectivities (up to 98% ee). Notably, this catalytic system can be recycled up to seven cycles.
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Zhao et al. (2010) studied this question.
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