Bottom‐Up Synthesis of Necklace‐Like Graphene Nanoribbons

Graphene nanoribbons (GNRs) with an unprecedented "necklace-like" structure were synthesized through a bottom-up chemical approach, based on the oxidative cyclodehydrogenation of tailor-made polyphenylene precursors. A polycyclic aromatic hydrocarbon consisting of 84 sp(2) carbons (C84) was also synthesized and characterized as a model compound. Characterizations by a combination of MALDI-TOF MS and FTIR, Raman, and UV/Vis absorption spectroscopy validated the formation of the necklace-like GNRs. The absorption spectrum and DFT calculations revealed a bandgap of approximately 1.4 eV for this novel GNR system, which has not been attained with other GNR structures, enabling further fine-tuning of GNR bandgaps by structural modulation.