The supramolecular conductor (Me-3,5-DIP)[Ni(dmit) 2 ] 2, which was prepared by electrochemical oxidation, consists of two crystallographically independent layers of Ni(dmit) 2 anions (Layers I and II). The tight-binding band calculation suggests that Layer I is in a Mott insulating state to include localized spins, and Layer II displays two-dimensional metallic conduction. The coexistence of the two contrastive molecular π-electrons of Ni(dmit) 2 anions is evidenced by electrical resistivity and magnetic susceptibility measurements.
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Kosaka et al. (2007) studied this question.
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