Homolytic Substitution (SH2) versus Triplet Diradical (ISC) in the Photochemical Denitrogenation of a DBH Azoalkane: Temperature-Dependent syn/anti Diastereoselectivity as a Mechanistic Probe for the Doubly Inverted Housane

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTHomolytic Substitution (SH2) versus Triplet Diradical (ISC) in the Photochemical Denitrogenation of a DBH Azoalkane: Temperature-Dependent syn/anti Diastereoselectivity as a Mechanistic Probe for the Doubly Inverted HousaneWaldemar Adam, Hermenegildo García, Vicente Martí, and Jarugu N. MoorthyView Author Information Institute of Organic Chemistry, University of Würzburg D-97074 Würzburg, Germany Instituto de Tecnología Química CSIC-UPV Apartado 22012, 46071-Valencia, Spain Cite this: J. Am. Chem. Soc. 1999, 121, 40, 9475–9476Publication Date (Web):September 24, 1999Publication History Received25 June 1999Revised25 August 1999Published online24 September 1999Published inissue 1 October 1999https://pubs.acs.org/doi/10.1021/ja992185jhttps://doi.org/10.1021/ja992185jrapid-communicationACS PublicationsCopyright © 1999 American Chemical SocietyRequest reuse permissionsArticle Views166Altmetric-Citations10LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information SUBJECTS:Crystal cleavage,Isomerization,Molecular structure,Photodissociation,Physical and chemical processes Get e-Alerts