We have investigated the adsorption of benzene on oriented single-domain Si(001)-(2×{}1) surfaces at room temperature by means of fully polarization-resolved near-edge x-ray-absorption fine-structure (NEXAFS) experiments. The present study reveals that benzene chemisorbs in a stable cyclohexadienelike configuration, labeled as a ``butterfly'' in the literature, which is di-{σ} bonded to silicon atoms.
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Witkowski et al. (2003) studied this question.
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