Small‐angle x‐ray scattering from solutions was applied in assessing branching using well‐characterized dextran hydrolyzates. It was found that the longitudinal and cross‐sectional properties of the polysaccharides vary in a manner predictable by the molecular topology of the chains. A hydrodynamically equivalent linear model for dextran is proposed and it has been shown that this model correctly predicts values of Φ and K, Flory's universal hydrodynamic constant and the Flory–Fox–Schaefgen parameter, respectively.
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Garg et al. (1978) studied this question.
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