⌘+K

Pulse Explore Communities Researchers Journals

Home Communities Explore

October 19, 2006Organometallics

Catalytic Alkene Hydroboration Mediated by Cationic and Formally Zwitterionic Rhodium(I) and Iridium(I) Derivatives of a P,N-Substituted Indene

Judy Cipot Christopher M. Vogels Robert McDonald Stephen A. Westcott Mark Stradiotto

View at Publisher

Ask AI

Bookmark

Share

Ask about this paper

Answers are grounded in this paper and cite their sources.

Ask your own question…

Abstract

Cationic ( 2a, b ) and formally zwitterionic ( 3a, b ) Rh(I) and Ir(I) complexes supported by P,N-substituted indene or indenide ligands (respectively) have been employed in the selective hydroboration of substituted vinylarenes with pinacolborane (HBpin, pin = 1,2-O 2 C 2 Me 4 ). Notably, 3a, b exhibited remarkably high, but differing, selectivities in the hydroboration of 1-phenylpropene.

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Cipot et al. (2006) studied this question.

synapsesocial.com/papers/6a951ce51ff8c23876f22136 https://doi.org/10.1021/om060742m

View at Publisher

Ask AI

Bookmark

Share

Keep reading

Synapse has enriched 10 related papers. Consider them for comparative context:

1Element−Element Additions to Unsaturated Carbon−Carbon Bonds Catalyzed by Transition Metal ComplexesOriginal Research · 2006 · 552 citations
2Asymmetric Hydrogenation of Unfunctionalized, Purely Alkyl-Substituted OlefinsOriginal Research · 2005 · 324 citations
3Dihydrido olefin and solvento complexes of iridium and the mechanisms of olefin hydrogenation and alkane dehydrogenationOriginal Research · 1982 · 189 citations
4Preparation and catalytic properties of some cationic iridium(III) and rhodium(III) dihydrido complexesOriginal Research · 1969 · 143 citations
5Enantioselective Hydrogenation of Alkenes with Iridium–PHOX Catalysts: A Kinetic Study of Anion EffectsOriginal Research · 2004 · 201 citations
6Rhodium Complexes with the New Anionic Diphosphine [7,8-(PPh2)2-7,8-C2B9H10]-LigandOriginal Research · 1996 · 38 citations
7Hydrogenation of Arenes over Silica-Supported Catalysts That Combine a Grafted Rhodium Complex and Palladium Nanoparticles: Evidence for Substrate Activation on Rh<sub>s</sub><sub>ingle</sub><sub>-</sub><sub>s</sub><sub>ite</sub>−Pd<sub>m</sub><sub>etal</sub> MoietiesOriginal Research · 2006 · 74 citations
8Photoinduced C−H Activation and Catalytic Carbonylation of Benzene − New Features of a Tris(pyrazolyl)methanesulfonato (Tpms) Rhodium(I) ComplexOriginal Research · 2001 · 22 citations
9Architecturally Distinctive Chiral-at-Rhenium Complexes with P═O/N:, P═O/P═O and S═O/S═O Donor Moieties: Syntheses, Structures, Reactivity, and Gas Phase Brønsted BasicitiesOrganometallics · 2026
10Flash Communication: Cooperative C–Cl Bond Activation of Dichloromethane by Heterobimetallic Ir(I)–M(IV) Pairs (M = Mo, W)Organometallics · 2026

More from Organometallics

More from University of Alberta

More from Dalhousie University

More from Mount Allison University