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August 31, 2026International Journal of Environmental Science and TechnologyOpen Access

Fast adsorption of Mn2+ and Zn2+ on commercial LTA zeolite: kinetics, equilibrium, and preliminary reuse assessment

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Authors

ASAllef Leite dos SantosTCT. S. CostaTMT. L. M. Moura

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Overview

Experimental study demonstrates rapid manganese and zinc removal by LTA zeolite via ion exchange, indicating safe agricultural reuse potential as micronutrients.

Key Points

  • To evaluate the adsorption kinetics, equilibrium mechanisms, and post-adsorption reuse safety of commercial LTA-type zeolite for removing aqueous divalent manganese and zinc.
  • Characterized Mn2+ and Zn2+ uptake kinetics and equilibrium isotherms using pseudo-second-order and Langmuir modeling alongside stoichiometric Na+ release measurements.
  • Assessed acute phytotoxicity through Cucumis sativus seed germination assays to determine whether metal-loaded zeolites could be repurposed as micronutrient fertilizers.
  • Zeolite uptake reached near-equilibrium within the first minute, with Zn2+ occupying exchange sites faster than Mn2+.
  • Adsorption followed Langmuir monolayer equilibrium and pseudo-second-order kinetics, driven primarily by Na+/divalent cation framework exchange rather than external surface area.
  • Germination assays with Cucumis sativus revealed no acute phytotoxic effects from metal-loaded zeolites, demonstrating potential for safe post-treatment reuse.

Cite This Study

Santos et al. (2026) studied this question.

synapsesocial.com/papers/6a954238f20e493292a745ebhttps://doi.org/10.1007/s13762-026-07390-z
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