Integrative Self‐Sorting Synthesis of a Fe8Pt6L24 Cubic Cage

96 bonds were formed when 62 building blocks (heterotopic ligands with FeII and PtII ions) self-assembled in a one-pot reaction into a heterometallic Fe8Pt6L24 cubic cage (see model, Fe purple, Pt orange, N blue). The dynamic nature of this method also allowed an efficient cage-to-cage conversion: a tetrahedral Fe4L6 cage was converted into the Fe8Pt6L24 cube, which was subsequently converted into a second tetrahedral Fe4L′6 cage.