Experimental study reveals molecular interactions in propiophenone and 2-alkoxy ethanol mixtures across varying temperatures, indicating hydrogen bonding between components.
Densities , viscosities and ultrasonic speeds of soundof binary mixtures of Propiophenone (PPH) with 2-Alkoxy Ethanols [2-Methoxy Ethanol, 2-Ethoxy Ethanol, 2-Butoxy Ethanol] have beenmeasured over the entire composition range from 303.15K to 318.15K and at atmospheric pressure 0.1MPa. Theworked out experimental data has been used to calculate various acoustical parameters like excess molar volume V E , excess ultrasonic velocity U E , acoustic impedance Z, excess acoustic impedance (Z E ), isentropic compressibility K S, excess isentropic compressibility , intermolecular free length L f, excess intermolecular free-length ( ), deviation in viscosity were calculatedand the computed results were fitted with the Redlich Kister equation to estimate the binary coefficients and standard deviation between experimental and calculated data.At different concentrations, FTIR analysis has been done for the above binary mixtures to confirm the hydrogen bonding presence.
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Devi et al. (2017) studied this question.
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