Pyramidal molecular hosts related to cyclotriveratrylene (CTV) form self-assembled cages including organic cages, hydrogen-bonded cages, and metallocages. The latter include M3L2, M4L4, M6L8, and M12L8 assemblies, including topologically complicated structures. Metallocages may show ligand exchange and/or homochiral sorting of the C3-symmetric CTV-analog ligands. Cages also occur within coordination networks. Pyramidal molecular hosts related to cyclotriveratrylene (CTV) form self-assembled cages including organic cages, hydrogen-bonded cages and metallocages. The latter include M3L2, M4L4, M6L8, and M12L8 assemblies with some topologically complicated structures. Metallocages may show ligand-exchange and/or homochiral sorting of the C3-symmetric CTV-analogue ligands. Cages also occur within coordination networks.
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Michaele J. Hardie (2016) studied this question.
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