A flexible host: The use of pyridyl-substituted cyclotriveratrylene ligands coupled with geometrically accommodating silver centers has resulted in the isolation and structural characterization of a compact [M2L2] molecular capsule and an [M4L4] tetrahedral prism (see structure). The former incarcerates two coordinated CH3CN molecules while the latter has an unusual star-burst shape and also acts as host for CH3CN molecules.
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Sumby et al. (2005) studied this question.
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