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An interesting metallo-organic polymeric architecture of a Zn(II) dinuclear pendant-armed macrocyclic complex was obtained. The structure consists of a supramolecular architecture of infinite pillars comprised of [Zn 2 L(NO 3 ) 2 ] 2+ units and free nitrate ions. This structure has tubular channels along the c -axis, and these are stabilized by the presence of multiple inter- and intramolecular π,π-stacking interactions. A flow of uncoordinated nitrate anions is present within the channels.
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Valencia et al. (2008) studied this question.
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