Dissolution of the highpolyphosphate coacervates of magnesium, calcium and aluminum was studied in order to understand the conformational feature of polyphosphate chains in the coacervates. Electrical conductivity and viscosity of the coacervate solutions were measured. Paper chromatographic technique was employed for the analysis of the solutions. It was concluded that the polyphosphates dissolve into acid solvents without cleavage of phosphate chains, the degree in the extension of the chains being considerably small. Dissolution processes of the three coacervates were compared. Optimum conditions on the syntheses of the threadforming coacervates are given.
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Kanazawa et al. (1974) studied this question.
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