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March 19, 2003The Journal of Organic Chemistry

Systematic Enantiomeric Separation of [60]Fullerene Bisadducts Possessing an Inherent Chiral Addition Pattern

Yosuke Nakamura Kyoji O‐kawa Tatsuya Nishimura Eiji Yashima Jun Nishimura

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Abstract

The optical resolution of trans-2 and trans-3 [60]fullerene bisadducts with an inherent chiral addition pattern, modified by Bingel reaction, cycloaddition by benzyne, Prato reaction, and cycloaddition by o-quinodimethane, was systematically investigated by using chiral HPLC columns (Chiralcel OD and Chiralpak AD). The chiroptical properties of enantiomers separated were also examined.

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Nakamura et al. (2003) studied this question.

synapsesocial.com/papers/6a9552bd57dad826d8f5a0d7 https://doi.org/10.1021/jo026657f

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